Calcium Bromide - Synthesis, Structure, and Reactions

Synthesis, Structure, and Reactions

It is produced by the reaction of calcium oxide, calcium carbonate with hydrobromic acid or the reaction of calcium metal with elemental bromine.

It adopts the rutile structure, featuring octahedral Ca centres bound to six bromide anions, which also bridge to other Ca centres.

When strongly heated in air, calcium bromide will produce calcium oxide and bromine:

2 CaBr2 + O2 → 2 CaO + 2 Br2

In this reaction the oxygen oxidizes the bromide to bromine.

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