Brillouin Scattering - Relationship To Raman Scattering

Relationship To Raman Scattering

Raman scattering is another phenomenon involving inelastic scattering processes of light with vibrational properties of matter. The detected frequency shift range and type of information extracted from the sample, however, are very different. Brillouin scattering denominates the scattering of photons from low-frequency phonons, while for Raman scattering photons are scattered by interaction with vibrational and rotational transitions in single molecules. Therefore the two techniques provide very different information about the sample: Raman spectroscopy is used to determine the chemical composition and molecular structure, while Brillouin scattering measures properties on a larger scale – such as the elastic behaviour. Experimentally, the frequency shifts in Brillouin scattering are detected with an interferometer, while Raman setup can be based on either interferometer or dispersive (grating) spectrometer.

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