Borane - Naming Conventions

Naming Conventions

The naming of neutral boranes is illustrated by the following examples, where the Greek prefix shows the number of boron atoms and the number of hydrogen atoms is in brackets:

  • B5H9 pentaborane(9)
  • B6H12 hexaborane(12)


The naming of anions is illustrated by the following, where the hydrogen count is specified first followed by the boron count, and finally the overall charge in brackets:

  • B5H8− octahydropentaborate(1−)


Optionally closo− nido− etc. (see above) can be added:-

  • B5H9, nido−pentaborane(9)
  • B4H10, arachno−tetraborane(10)
  • B6H62−, hexahydro−closo−hexaborate(2−)

Understandably many of the compounds have abbreviated common names.

Read more about this topic:  Borane

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