Azeotrope - Examples of Azeotropes

Examples of Azeotropes

Proportions are by weight.

  • nitric acid (68%) / water, boils at 120.5°C at 1 atm (negative azeotrope)
  • perchloric acid (28.4%) / water, boils at 203°C (negative azeotrope)
  • hydrofluoric acid (35.6%) / water, boils at 111.35°C (negative azeotrope)
  • ethanol (96%) / water, boils at 78.1°C
  • sulfuric acid (98.3%) / water, boils at 338°C
  • acetone / methanol / chloroform form an intermediate boiling (saddle) azeotrope
  • diethyl ether (33%) / halothane (66%) a mixture once commonly used in anaesthesia.
  • benzene / hexafluorobenzene forms a double binary azeotrope.

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