Atomic, Molecular, and Optical Physics - Modern Treatments

Modern Treatments

The largest steps towards the modern treatment was the formulation of quantum mechanics with the matrix mechanics approach, by Werner Heisenberg and the discovery of the Schrödinger equation by Erwin Schrödinger.

There are a variety of semi-classical treatments within AMO. Which aspects of the problem are treated quantum mechanically and which are treated classical is dependent on the specific problem at hand. The semi-classical approach is ubiquitous in computational work within AMO, largely due to the large decrease in computational cost and complexity associated with it.

For matter under the action of a laser, a fully quantum mechanical treatment of the atomic or molecular system is combined with the system being under the action of a classical electromagnetic field. Since the field is treated classically it can not deal with spontaneous emission. This semi-classical treatment is valid for most systems, particular those under the action of high intensity laser fields. The distinction between optical physics and quantum optics is the use of semi-classical and fully quantum treatments respectively.

Within collision dynamics and using the semi-classical treatment, the internal degrees of freedom may be treated quantum mechanically, whilst the relative motion of the quantum systems under consideration are treated classically. When considering medium to high speed collisions, the nuclei can be treated classically while the electron is treated quantum mechanically. In low speed collisions the approximation fails.

Classical Monte-Carlo methods for the dynamics of electrons can be described as semi-classical in that the initial conditions are calculated using a fully quantum treatment, but all further treatment is classical.