Aluminium Bromide - Synthesis

Synthesis

By far the most common form of aluminium bromide is Al2Br6. This species exists as hygroscopic colorless solid at standard conditions. Typical impure samples are yellowish or even red-brown due to the presence of iron-containing impurities. It is prepared by the reaction of HBr with Al:

2 Al + 6 HBr → Al2Br6 + 3 H2

Alternatively, the direct bromination occurs also:

2 Al + 3 Br2 → Al2Br6

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