The 2007 National League Division Series (NLDS), the opening round of the 2007 National League playoffs, began on Wednesday, October 3 and ended on Saturday, October 6, with the champions of the three NL divisions and one wild card team participating in two best-of-five series. They were:
- (1) Arizona Diamondbacks (Western Division champions, 90–72) vs. (3) Chicago Cubs (Central Division champions, 85–77): Diamondbacks win series, 3–0.
- (2) Philadelphia Phillies (Eastern Division champions, 89–73) vs. (4) Colorado Rockies (Wild Card qualifier, 90–73): Rockies win series, 3–0.
Colorado earned the wild card after winning a one-game playoff with San Diego. Although the division winner with the best record normally plays the wild card team, the Diamondbacks played the Cubs, rather than the wild card Rockies, because the league does not pair teams from the same division against each other in the division series.
Both series represented the first time the opponents had met in the postseason, and the Rockies' victory was their first in any postseason series. The Diamondbacks and the Rockies met in the NL Championship Series, with the Rockies becoming the National League champion and going on to face the American League champion in the 2007 World Series. This was the first time under the expanded playoffs format first used in 1995 that two teams from the National League's Western Division had played against one another in the NLCS.
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